The clash will be the first between the clubs since Leeds were relegated from the top flight in 2004.
Liverpool have won more League Cup's (7) and appeared in more finals (10) than any other club.
Full draw
Arsenal v West Bromwich Albion
Aston Villa v Cardiff City
Barnsley v Burnley
Bolton Wanderers v West Ham United
Carlisle United v Portsmouth
Chelsea v Queens Park Rangers
Hull City v Everton
Leeds United v Liverpool
Manchester City v Fulham
Manchester United v Wolverhampton Wanderers
Nottingham Forest v Blackburn Rovers
Peterborough United v Newcastle United
Preston North End v Tottenham Hotspur
Scunthorpe United v Port Vale
Stoke City v Blackpool
Sunderland v Birmingham City